Addition of silylated nucleophiles to α-oxoketenes.
نویسندگان
چکیده
A general evaluation of silylated nucleophiles to intercept transient α-oxoketenes generated by microwave-assisted Wolff rearrangement of 2-diazo-1,3-dicarbonyl compounds is presented. Original scaffolds and synthetic intermediates are accessed in a rapid, efficient and easy-to-handle way. Mechanistic studies by DFT calculations and some post-functionalizations are discussed.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 14 شماره
صفحات -
تاریخ انتشار 2016